Tetrahedron Letters p. 6045 - 6048 (1987)
Update date:2022-07-29
Topics:
Barre, V.
Uguen, D.
The allylic thiosulfones 2 resulting from the addition of thiols to propargylic sulfone 1 have been used to convert enones into diketo-sulfones which then led to bicyclo alkanediones by either tris-anionization then cupric oxidation or treatment with rhodium acetate of the corresponding diazoketo-sulfone.
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