Highly stereoselective reduction of methyl ketone complexes of the chiral Lewis acid 5-C5H5)Re(NO)(PPh3)>+ by K(s-C4H9)3BH; synthesis of optically active secondary alcohols and derivatives

DOI: 10.1016/0022-328X(89)87307-3

Source and publish data:

Journal of Organometallic Chemistry p. C17 - C28 (1989)

Update date:2022-07-29

Topics:

Authors:

Dalton, Dennis M.

Gladysz, J. A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(89)87307-3

Reaction of optically active ketone complexes (+)-(R)-<(η⁵-C5H5)Re(NO)(PPh3)(η¹-O=C(R)CH3)>⁺BF^- (R=CH2CH3, CH(CH3)2, C(CH3)3, C6H5) with K(s-C4H9)3BH gives alkoxide complexes (+)-(RS)-(η⁵-C5H5)Re(NO)(

Full text of DOI:10.1016/0022-328X(89)87307-3

Products guided by the article

Product name:(RR)-C(CH₃)(CH(CH₃)2)HOCOC(CF₃)(C₆H₅)(OCH₃)

Cas No:20445-07-2

R&D Labs maybe for 20445-07-2

Hangzhou Gangjin Chemical Co.,Ltd.(expird)

Contact:+86-571-85109780

Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China
Anyang Double Circle Auxiliary CO.,LTD

Contact:0086-134 6082 4403

Address:dongfeng road, anyang city, henan province,china
Xi'an Kaixiang Photoelectric Technology Co., Ltd

website:http://www.kxmaterials.com/

Contact:86-29-15991651477

Address:Building 6, Biopharmaceutical Industry R&D Cluster Base, No. 16, Caotang 4th Road, Caotang Science and Technology Industrial Base, High-tech Zone, Xi'an City, Shaanxi Province, China
Zhejiang Chemline International Co., Ltd.

Contact:+86-571-88062298

Address:Hengdian Industry Area, Dongyang, Zhejiang, China
Chongqing KonAo Health Co.,Ltd

Contact:13687578375

Address:wuhan hubei china

Relevant to this article

Ribosome-mediated incorporation of hydrazinophenylalanine into modified peptide and protein analogues

Doi:10.1021/ja974066e
(1998)
Syntheses and kinetic evaluation of hydroxamate-based peptide inhibitors of glyoxalase I

Doi:10.1016/S0960-894X(98)00116-4
(1998)
Stereochemically non-rigid transition metal complexes of 2,6-bis[1-(phenylimino)ethyl]pyridine (BIP). Part 3. Dynamic NMR studies of fac-[PtXMe₃(BIP)] (X=C1, Br, or I). Crystal structure of fac-[PtIMe₃(BIP)]

Doi:10.1016/S0022-328X(97)00690-6
(1998)
Reactivity studies of (^tBu₃SiNH)(^tBu ₃SiN=)₂WH including anionic derivatives featuring the tris-tri- tert -butylsilylimide tungsten core

Doi:10.1021/om200597z
(2011)
Platinum-Catalyzed Silaborative Coupling of 1,3-Dienes to Aldehydes: Regio- and Stereoselective Allylation with Dienes through Allylic Platinum Intermediates

Doi:10.1021/ja980373o
(1998)
Ruthenium-mediated selective head-to-tail dimerization of acrylic and α,β-unsaturated carbonyl compounds: Generation of an acrylate-hydride complex C₅Me₅Ru(PCy₃)(CH₂=CHCO ₂Et)H

Doi:10.1016/S0022-328X(97)00591-3
(1998)

Article Doi