Highly stereoselective reduction of methyl ketone complexes of the chiral Lewis acid 5-C5H5)Re(NO)(PPh3)>+ by K(s-C4H9)3BH; synthesis of optically active secondary alcohols and derivatives

DOI: 10.1016/0022-328X(89)87307-3

Source and publish data:

Journal of Organometallic Chemistry p. C17 - C28 (1989)

Update date:2022-07-29

Topics:

Authors:

Dalton, Dennis M.

Gladysz, J. A.

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Article abstract of DOI:10.1016/0022-328X(89)87307-3

Reaction of optically active ketone complexes (+)-(R)-<(η⁵-C5H5)Re(NO)(PPh3)(η¹-O=C(R)CH3)>⁺BF^- (R=CH2CH3, CH(CH3)2, C(CH3)3, C6H5) with K(s-C4H9)3BH gives alkoxide complexes (+)-(RS)-(η⁵-C5H5)Re(NO)(

Full text of DOI:10.1016/0022-328X(89)87307-3

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