Tetrahedron p. 3243 - 3254 (1998)
Update date:2022-07-29
Topics:
Sarkar, Tarun K.
Mukherjee, Bireswar
Ghosh, Sunil K.
An enantiospecific route to jasmonoid natural products, (+) - methyl epijasmonate and (-) -methyl cucurbate from L-glutamic acid is reported. The key step is a 5-(3,4) ene cyclization of a functionalized 1,6-diene as chiron, which sets up three chiral centres with a high degree of diastereoselectivity.
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