Acid-promoted rearrangement of α,β-epoxy acylates: Remarkable effects of an acyl group and a Lewis acid

DOI: 10.1016/S0040-4039(96)02468-9

Source and publish data:

Tetrahedron Letters p. 1061 - 1064 (1997)

Update date:2022-07-29

Topics:

Authors:

Kita, Yasuyuki

Kitagaki, Shinji

Yoshida, Yutaka

Mihara, Sachiko

Fang, Dai-Fei

Fujioka, Hiromichi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(96)02468-9

Remarkable steric and electrostatic effects of acyl groups and exceptionally bulky Lewis acid, (MABR), which make the rearrangement reaction applicable to various types of reaction systems including acyclic ones in the acid-promoted rearrangement of α,β-epoxy acylates, were found.

Full text of DOI:10.1016/S0040-4039(96)02468-9

Products guided by the article

Product name:(3-Cyclohexyl-2,3-dimethyl-oxiranyl)-methanol

Cas No:205121-51-3

R&D Labs maybe for 205121-51-3

Taizhou Green Peptide Trading Co., Ltd.

Contact:--15314709780

Address:Room 1501, No71, Yuehe Road, Taizhou City, Zhejiang Province, China
HuiFeiChem PharmaTech Co.Ltd

Contact:0510-85393305

Address:1619 Huishan Avenue, Huishan District, Wuxi,
Water Chemical Co.,LTD

Contact:+86-21-6856-1349 523-87676172

Address:No16 . BinJiang Road . Taixing Economy Developing Area .JiangSu Province . China
Tianjin Emulsion Science&Technology Development Co.,Ltd

Contact:13901380442

Address:Vake Garden New Town New Yi Bai Road Beichen District Tianjin,China

Relevant to this article

Aldol type reaction of unprotected sugars in methanol

Doi:10.1016/0040-4039(94)02377-N
(1995)
Optical resolution of 3-(silyloxy)glutaric acid half esters and their utilization for enantioconvergent synthesis of a HMG-CoA reductase inhibitor

Doi:10.1021/jo9722156
(1998)
Influence of Co²⁺ and Cu²⁺ on the phase composition of Zn-Ni alloy

Doi:10.1016/j.electacta.2006.01.064
(2006)
Low-temperature preparation of tungsten halide clusters: Crystal structure of the adduct W₅Br₁₂ · SbBr₃¹

Doi:10.1134/S1070328412020078
(2012)
New, simple total syntheses of benzo[b]naphtho[2,3-d]furan-6,11-diones and benzo[b]naphtho[2,1-d]furans

Doi:10.1016/S0040-4039(98)00167-1
(1998)
Unusual degradation of the rhenium silyl ester Cp(NO)(PPh₃)ReCO₂SiMe₂Ph to the bimetallic μ-η¹(C(Re)):η¹(O,O′(Re)) carbon dioxide complex Cp(NO)(PPh₃)ReCO₂Re(NO)(CO)(PPh₃)OSiMe ₂Ph

Doi:10.1021/om970831m
(1998)

Article Doi