Chemistry Letters p. 397 - 398 (1998)
Update date:2022-07-29
Topics:
Hiroi, Kunio
Kato, Fumiko
Yamagata, Akiko
Asymmetric direct α,β-functionalization of allenes with chiral phosphine ligands was successfully achieved with extremely high enantioselectivity via asymmetric carbopalladation to the racemic allenes. The same palladium-catalyzed alkylation of a chiral allene was executed with complete enantiospecificity. The stereochemistry of this reaction was determined and the mechanism of this asymmetric induction is proposed.
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(1998)
