Journal of Organometallic Chemistry p. 2427 - 2433 (2009)
Update date:2022-08-04
Topics:
Garcia, Julien
Meyer, Daniel J.M.
Guillaneux, Denis
Moreau, Jo?l J.E.
Wong Chi Man, Michel
Titanium-catalysed dehydrocondensation and hydrosilylation of primary, secondary and tertiary phenylsilanes have been investigated in a one-pot process with Cp2Ti(OPh)2 as catalyst by NMR studies. Only primary and secondary silanes were found to undergo simultaneous dehydrogenative coupling and hydrosilylation reactions to produce the functional polysilanes.
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