The Rh2(OAc)4 catalysed C-H insertion in chiral ester diazoanilides

DOI: 10.1016/0040-4039(95)02115-9

Source and publish data:

Tetrahedron Letters p. 145 - 148 (1996)

Update date:2022-08-03

Topics:

Authors:

Wee, Andrew G.H.

Liu, Baosheng

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)02115-9

The Rh₂(OAc)₄-catalysed C-H insertion in chiral ester diazoanilides was investigated and was found to yield 4-substituted 2-pyrrolidinones with moderate to high e.e. (37-98%) after decarbalkoxylation. Electronic effects were found to oppose steric effects in influencing the enantioselectivity of the reaction in N-arylethyl diazoanilides.

Full text of DOI:10.1016/0040-4039(95)02115-9

Products guided by the article

Product name:N-(4-Methoxy-phenyl)-N-[2-(4-nitro-phenyl)-ethyl]-malonamic acid (1R,2S,3S,4R)-4,7,7-trimethyl-3-naphthalen-1-yl-bicyclo[2.2.1]hept-2-yl ester

Cas No:210585-41-4

R&D Labs maybe for 210585-41-4

Shaanxi HuaTai Bio-fine chemical company Ltd

Contact:86-029-87862197

Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
Zhejiang Allied Chemical Co.,Ltd

Contact:18967038207

Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
Tianjin Te-An Chemtech Co., Ltd.(expird)

Contact:+86-22-65378638

Address:A5-8, No.80 Haiyun Street, TEDA
Antimex Chemical Limied

website:http://www.antimex.com

Contact:0086-21-50563169

Address:Room1027,No.Jinyu Road,Pudong
Shanghai Longschem Co.,Ltd

Contact:021-36356756

Address:Room601,Building No.14,280 Yangcheng Road,Shanghai

Relevant to this article

Ferrocenic polyphosphines and polythioethers: Synthesis, reactivity and structure

Doi:10.1016/S0022-328X(98)00551-8
(1998)
Doi:10.1038/2061038b0
(1965)
Measurement of interglycosidic ³J(CH) coupling constants of selectively ¹³C labeled oligosaccharides by 2D J-resolved ¹H NMR spectroscopy

Doi:10.1016/S0008-6215(98)00047-0
(1998)
Novel 4-piperidinopyridine inhibitors of oxidosqualene cyclase-lanosterol synthase derived by consideration of inhibitor pK_a

Doi:10.1016/S0960-894X(01)00423-1
(2001)
Isoquinolinium N-arylimides and some cycloadditions to heterocumulenes

Doi:10.1002/(SICI)1099-0690(199802)1998:2<379::AID-EJOC379>3.0.CO;2-F
(1998)
C₅Me₅/ER-Ligated samarium(II) complexes (ER=OAr, SAr, NR¹R²): A new type of olefin polymerization catalysts Presented at the 22nd Rare Earth Research Conference, Argonne, July 10-15, 1999 (Abstract No. E-2)

Doi:10.1016/S0925-8388(00)00654-X
(2000)

Article Doi