Stereoselective dihydroxylation of 2-alkyl- and 2,4-dialkyl-2-amido-3- cyclohexen-1-ones. Synthesis of enantiomerically related 2-alkyl- and 2,4- dialkyl-3-hydroxy-1-oxocyclohexan-2,4-carbolactones by complementary butyrolactonization reactions

DOI: 10.1016/S0040-4039(98)01440-3

Source and publish data:

Tetrahedron Letters p. 6663 - 6666 (1998)

Update date:2022-07-30

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Authors:

Schultz, Arthur G.

Dai, Mingshi

Tham, Fook S.

Zhang, Xuqing

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Article abstract of DOI:10.1016/S0040-4039(98)01440-3

Stereoselective dihydroxylation of 2a-2f gives cis-diols 3a-3f, from which hydroxylactones 5a-5f are obtained by an acid-catalyzed process involving retro aldol-realdolization prior to transesterification.

Full text of DOI:10.1016/S0040-4039(98)01440-3

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