
Tetrahedron Letters p. 4983 - 4986 (1998)
Update date:2022-08-05
Topics:
Dankwardt, John W.
Dankwardt, Sharon M.
Schlessinger, Richard H.
The synthesis of the C-28 through C-38 segment of the marine natural product okadaic acid was accomplished employing a highly enantio- and diasteroselective aldol condensation reaction of a chiral vinylogous urethane enolate. The stereocenter at C-29 was addressed utilizing a diastereoselective hydroboration reaction.
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Doi:10.1080/00397919808004880
(1998)Doi:10.1021/ja01183a078
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(1998)