Tetrahedron Letters p. 5433 - 5436 (1998)
Update date:2022-08-03
Topics:
Macdonald, Gregor
Alcaraz, Lilian
Lewis, Norman J.
Taylor, Richard J. K.
An asymmetric approach to the mC7N epoxyquinone central unit of the manumycin antibiotics is described based on the enantioselective (89% ee) chiral phase transfer epoxidation of a substituted cyclohexenone. The chiral epoxide is employed in the trust syntheses of the title compounds in enantiomerically pure form.
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