Tetrahedron Letters p. 6787 - 6790 (1998)
Update date:2022-07-29
Topics:
Majewski, Marek
Shao, Jianxing
Nelson, Ken
Nowak, Pawel
Irvine, Nicholas M.
Three diastereoisomers of 1-deoxycastanospermine were synthesized in enantiomerically pure form. The key step in the synthesis involved reaction of lithiated N-Boc-pyrrolidine in the presence of sparteine with a chiral building block derived from tartaric acid.
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Doi:10.1002/hc.21273
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