Tetrahedron Letters p. 8179 - 8182 (1998)
Update date:2022-07-30
Topics: Synthesis NMR spectroscopy Catalyst Stereochemistry Alkene Isomer Exo-glycals
Griffin, Frank K.
Murphy, Paul V.
Paterson, Duncan E.
Taylor, Richard J.K.
A new route to exo-glycals is described which starts from S-glycoside dioxides and utilises Meyers' variant of the Ramberg-Backlund rearrangement. The methodology is successful with glucose, galactose, mannose, xylose, fucose and ribose derivatives, and has been used to prepare di-, tri- and tetra-substituted alkenes.
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Doi:10.1007/BF03343797
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(1998)
