Tetrahedron Letters p. 8179 - 8182 (1998)
Update date:2022-07-30
Topics: Synthesis NMR spectroscopy Catalyst Stereochemistry Alkene Isomer Exo-glycals
Griffin, Frank K.
Murphy, Paul V.
Paterson, Duncan E.
Taylor, Richard J.K.
A new route to exo-glycals is described which starts from S-glycoside dioxides and utilises Meyers' variant of the Ramberg-Backlund rearrangement. The methodology is successful with glucose, galactose, mannose, xylose, fucose and ribose derivatives, and has been used to prepare di-, tri- and tetra-substituted alkenes.
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Doi:10.1007/BF03343797
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(2015)Doi:10.1016/S0960-894X(98)00473-9
(1998)Doi:10.1039/j39690000355
(1969)Doi:10.1002/ardp.19522850106
(1952)Doi:10.1021/jo981203x
(1998)
