Formation of 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol and 2- (m-chlorobenzoyloxy)-3-(phenylseleno)propan-1-ol from a reaction of allyl phenyl selenide with m-chloroperoxybenzoic acid

DOI: 10.1016/S0040-4039(98)02020-6

Source and publish data:

Tetrahedron Letters p. 8877 - 8880 (1998)

Update date:2022-09-26

Topics:

Authors:

Hirose, Takanori

Morita, Nobuhiro

Asakura, Mitsuhiro

Kitahara, Keisuke

Toyota, Shinji

Oki, Michinori

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Article abstract of DOI:10.1016/S0040-4039(98)02020-6

Oxidation of allyl phenyl selenide with m-chloroperoxybenzoic acid unexpectedly afforded two compounds, the structures of which were determined as 3-(m-chlorobenzoyloxy)-2-(phenylseleno)propan-1-ol and 2-(m- chlorobenzoyloxy)-3-(phenylseleno)propan-1-ol. Structure determination of the products is described and the possible mechanisms are discussed.

Full text of DOI:10.1016/S0040-4039(98)02020-6

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