A novel asymmetric synthesis of 2,5-dialkylpyrrolidines

DOI: 10.1016/S0040-4039(99)00058-1

Source and publish data:

Tetrahedron Letters p. 1657 - 1660 (1999)

Update date:2022-08-03

Topics:

Authors:

Daley, Valerie

D'Angelo, Jean

Cave, Christian

Mahuteau, Jacqueline

Chiaroni, Angele

Riche, Claude

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Article abstract of DOI:10.1016/S0040-4039(99)00058-1

ZnCl₂-promoted cyclization of enamino ester 8 furnished a 1.5:1 mixture of pyrrolidines 9 and 10. NaBH₄-reduction of this mixture gave cis and trans-2,5-dialkylpyrrolidines 12 and 13 in the ratio 2:1. The latter derivative was obtain

Full text of DOI:10.1016/S0040-4039(99)00058-1

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