Chemistry Letters p. 1 - 2 (1998)
Update date:2022-07-29
Topics:
Shiina, Isamu
Iwadare, Hayato
Sakoh, Hiroki
Hasegawa, Masatoshi
Tani, Yu-Ichirou
Mukaiyama, Teruaki
Baccatin III was efficiently synthesized from the BC ring system of Taxol, 2α,10β-dibenzyloxy-11β-(t-butyldimethylsiloxy)-7β-hydroxy- 1α-(4-methoxybenzyloxy)-8β,15,15-trimethyl-4-methylene-trans- bicyclo[6.4.0]dodecan-9-one (1), by successive constructions of A and D rings via respective intramolecular pinacol coupling and oxetane forming reaction.
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