A new method for the synthesis of baccatin III

DOI: 10.1246/cl.1998.1

Source and publish data:

Chemistry Letters p. 1 - 2 (1998)

Update date:2022-07-29

Topics:

Authors:

Shiina, Isamu

Iwadare, Hayato

Sakoh, Hiroki

Hasegawa, Masatoshi

Tani, Yu-Ichirou

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1998.1

Baccatin III was efficiently synthesized from the BC ring system of Taxol, 2α,10β-dibenzyloxy-11β-(t-butyldimethylsiloxy)-7β-hydroxy- 1α-(4-methoxybenzyloxy)-8β,15,15-trimethyl-4-methylene-trans- bicyclo[6.4.0]dodecan-9-one (1), by successive constructions of A and D rings via respective intramolecular pinacol coupling and oxetane forming reaction.

Full text of DOI:10.1246/cl.1998.1

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Product name:(1R,2S,3R,5R,6S,7S,8S,9S)-2,6-Dibenzyloxy-5-(tert-butyldimethylsiloxy)-7,9-(isopropylidenedioxy)-4,4,8-trimethyl-12-methylenebicyclo[6.4.0]dodecan-3-ol

Cas No:222726-95-6

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