Russian Chemical Bulletin p. 1571 - 1573 (1998)
Update date:2022-08-05
Topics: Experimental Chemical terms Generation Capture
Basenko
Gebel
Voronkov
Klyba
Mirskov
Methyl(vinyl)dichlorosilane reacts with DMSO in the presence of hexamethyldisiloxane to give the corresponding linear oligosiloxanes of the general formula Me3Si(OSiMeVin)nOSiMe3 (n = 1-6) as well as MeSi(OSiMe3)3 and Me3Si(MeOSiVin)mOSi(OSiMe3)(Me)OSiMe 3 (m = 1-2). The same reaction in the presence of chlorotrimethylsilane results in oligomers of the general formula Me3Si(OSiMeVin)nCl (n = 1-3). A possible scheme of their formation is discussed.
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