Generation and capture of methyl(vinyl)silanone

Article abstract of DOI:10.1007/BF02495612

Methyl(vinyl)dichlorosilane reacts with DMSO in the presence of hexamethyldisiloxane to give the corresponding linear oligosiloxanes of the general formula Me₃Si(OSiMeVin)_nOSiMe₃ (n = 1-6) as well as MeSi(OSiMe₃)₃ and Me₃Si(MeOSiVin)_mOSi(OSiMe₃)(Me)OSiMe ₃ (m = 1-2). The same reaction in the presence of chlorotrimethylsilane results in oligomers of the general formula Me₃Si(OSiMeVin)_nCl (n = 1-3). A possible scheme of their formation is discussed.