Fast Cis-Trans Isomerization of Square-Planar Bis(diethyl sulfide)platinum(II) Complexes. Reaction of cis-Dichlorobis(diethyl sulfide)platinum(II) with Mesityllithium

DOI: 10.1246/bcsj.60.797

Source and publish data:

Bulletin of the Chemical Society of Japan p. 797 - 799 (1987)

Update date:2022-07-30

Topics:

Authors:

Tobita, Hiromi

Habazaki, Hiroki

Ogino, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.60.797

Reaction of cis- with a slight excess of mesityllithium in benzene-ether mixture afforded trans- (Mes=2,4,6-trimethylphenyl; SEt2=diethyl sulfide) as a major product.When mesityllithium reagent containing lithium bromide was used, trans- was obtained.Acceleration of cis-trans isomerization in the presence of mesityllithium was observed.

Full text of DOI:10.1246/bcsj.60.797

Products guided by the article

Product name:{Pt2}

Cas No:22518-41-8

R&D Labs maybe for 22518-41-8

Onlychem (Jinan)Biotech Co.,Ltd

Contact:86-531-83175885

Address:No. 44, Honglou South Road, Jinan,China
NOVASYNCS CO., LTD

Contact:0512-63006287

Address:no.88.YISHENG Road,etdz-WUJIANG,SUZHOU,CHINA
ANHUI WEICHI CHEMICAL CO.,LTD

website:http://www.weichichem.com

Contact:+8613912949432

Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Jinan Jinguilin Chemical Co.,Ltd

Contact:+86-531-81188412

Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan
Zhejiang Kaili Industrial Co., Ltd

Contact:+86-571-85241926

Address:lantian business center,No.18 Moganshan Road

Relevant to this article

Nanoporous three-dimensional networks topologically related to Cooperite from the self-assembly of copper(I) centres and the 'square-planar' building block 1,2,4,5-tetracyanobenzene

Doi:10.1039/a809144g
(1999)
Doi:10.1016/S0022-328X(00)88036-5
(1969)
Studies on chromium trioxide-based oxidative coupling reagents and synthesis of lignan-cagayanone

Doi:10.1248/cpb.41.1507
(1993)
Stereoselective synthesis of an erythro N-protected α-amino epoxide derivative

Doi:10.1016/S0040-4039(99)00409-8
(1999)
cis- and trans-3-(3-indolyl)proline derivatives as conformationally restricted analogues of tryptophan

Doi:10.1055/s-1999-2708
(1999)
Prostanoids and related compounds. VII. Synthesis and inhibitory activity of 1-isoindolinone derivatives possessing inhibitory activity against thromboxane A₂ analog (U-46619)-induced vasoconstriction

Doi:10.1248/cpb.47.529
(1999)

Article Doi