Fast Cis-Trans Isomerization of Square-Planar Bis(diethyl sulfide)platinum(II) Complexes. Reaction of cis-Dichlorobis(diethyl sulfide)platinum(II) with Mesityllithium

DOI: 10.1246/bcsj.60.797

Source and publish data:

Bulletin of the Chemical Society of Japan p. 797 - 799 (1987)

Update date:2022-07-30

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Authors:

Tobita, Hiromi

Habazaki, Hiroki

Ogino, Hiroshi

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Article abstract of DOI:10.1246/bcsj.60.797

Reaction of cis- with a slight excess of mesityllithium in benzene-ether mixture afforded trans- (Mes=2,4,6-trimethylphenyl; SEt2=diethyl sulfide) as a major product.When mesityllithium reagent containing lithium bromide was used, trans- was obtained.Acceleration of cis-trans isomerization in the presence of mesityllithium was observed.

Full text of DOI:10.1246/bcsj.60.797

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