Fast Cis-Trans Isomerization of Square-Planar Bis(diethyl sulfide)platinum(II) Complexes. Reaction of cis-Dichlorobis(diethyl sulfide)platinum(II) with Mesityllithium

DOI: 10.1246/bcsj.60.797

Source and publish data:

Bulletin of the Chemical Society of Japan p. 797 - 799 (1987)

Update date:2022-07-30

Topics:

Authors:

Tobita, Hiromi

Habazaki, Hiroki

Ogino, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.60.797

Reaction of cis- with a slight excess of mesityllithium in benzene-ether mixture afforded trans- (Mes=2,4,6-trimethylphenyl; SEt2=diethyl sulfide) as a major product.When mesityllithium reagent containing lithium bromide was used, trans- was obtained.Acceleration of cis-trans isomerization in the presence of mesityllithium was observed.

Full text of DOI:10.1246/bcsj.60.797

Products guided by the article

Product name:{Pt2}

Cas No:22518-41-8

R&D Labs maybe for 22518-41-8

Shanghai AoBo Bio-Pharmaceutical Technology Co., Ltd.

Contact:+86-21-51320130-801, 816

Address:Room 601, No. 1011, Halei Road, Zhangjiang High-Tech Park, Pudong, Shanghai
JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road
Tianjin Jingye Fine Chemicals Co., Ltd.

Contact:+86-15722078107; +86-22-26911407

Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China
Beijing Century Richap Chemistry Co.,Ltd

Contact:+86- 010-64455497

Address:Guannan County, Lianyungang City, Jiangsu Province, China
Jiangxi Biochem Co.,Ltd

Contact:86-791-86629460

Address:1-6F, 118 Xinzhou road, Nanchang, Jiangxi, China

Relevant to this article

Nanoporous three-dimensional networks topologically related to Cooperite from the self-assembly of copper(I) centres and the 'square-planar' building block 1,2,4,5-tetracyanobenzene

Doi:10.1039/a809144g
(1999)
Doi:10.1016/S0022-328X(00)88036-5
(1969)
Studies on chromium trioxide-based oxidative coupling reagents and synthesis of lignan-cagayanone

Doi:10.1248/cpb.41.1507
(1993)
Stereoselective synthesis of an erythro N-protected α-amino epoxide derivative

Doi:10.1016/S0040-4039(99)00409-8
(1999)
cis- and trans-3-(3-indolyl)proline derivatives as conformationally restricted analogues of tryptophan

Doi:10.1055/s-1999-2708
(1999)
Prostanoids and related compounds. VII. Synthesis and inhibitory activity of 1-isoindolinone derivatives possessing inhibitory activity against thromboxane A₂ analog (U-46619)-induced vasoconstriction

Doi:10.1248/cpb.47.529
(1999)

Article Doi