Synthesis and reactions of some dinitrodiazoquinones

DOI: 10.1016/S0040-4020(99)00223-9

Source and publish data:

Tetrahedron p. 5581 - 5592 (1999)

Update date:2022-07-30

Topics:

Authors:

Bergman, Jan

Brimert, Thomas

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Article abstract of DOI:10.1016/S0040-4020(99)00223-9

Some novel highly substituted diazoquinones have been synthesised in one step from simple anilines by treatment with nitric acid in sulfuric acid solution. The reaction is proposed to proceed via an N,3,4,5- tetranitroaniline which on its reaction pathway undergoes a nitro-nitrito rearrangement.

Full text of DOI:10.1016/S0040-4020(99)00223-9

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Product name:3,5-dimethyl-2,6-dinitro-p-diazoquinone

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