
Tetrahedron Letters p. 4387 - 4390 (1999)
Update date:2022-08-03
Topics:
Ishihara, Jun
Yamamoto, Yuuko
Kanoh, Naoki
Murai, Akio
Construction of the left segment of azadirachtin in naturally occurring enantiomer is described. The key reaction is an intramolecular Diels-Alder reaction, which was performed under thermal conditions to afford the highly functionalized decalin compounds selectively.
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Doi:10.1021/jo01018a038
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(2015)