1,5-Induction in reactions of 4-alkoxy-2-trimethylsilylalk-2- enyl(tributyl)stannanes with aldehydes

DOI: 10.1016/S0040-4020(99)00442-1

Source and publish data:

Tetrahedron p. 8757 - 8768 (1999)

Update date:2022-07-29

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Authors:

Taylor, Nicholas H.

Thomas, Eric J.

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Article abstract of DOI:10.1016/S0040-4020(99)00442-1

2-Trimethylsilylalk-2-enylstannanes undergo tin(IV) chloride promoted reactions with aldehydes to give homoallylic alcohols with retention of the 2-trimethylsilyl group. 4-Alkoxy-2-trimethylsilylalk-2-enyl(tributyl)stannane 31 reacts with aldehydes under

Full text of DOI:10.1016/S0040-4020(99)00442-1

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