Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation

DOI: 10.1021/acs.orglett.1c00381

Source and publish data:

Organic Letters p. 2243 - 2247 (2021)

Update date:2022-07-30

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Authors:

Capaldo, Luca

Ravelli, Davide

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Article abstract of DOI:10.1021/acs.orglett.1c00381

A versatile approach for the alkynylation of a variety of aliphatic hydrogen donors, including alkanes, is reported. We used tetrabutylammonium decatungstate as photocatalyst to generate organoradicals from C-H/Si-H bonds via hydrogen atom transfer. The l

Full text of DOI:10.1021/acs.orglett.1c00381

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