Methyltriphenylphosphonium 2-methyl-1-sulfido-1,2-dicarba-closo-dodecaborane(12)

DOI: 10.1107/S0108270199006307

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 1581 - 1583 (1999)

Update date:2022-08-03

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Authors:

Kivekaes, Raikko

Benakki, Rajae

Vinas, Clara

Sillanpaeae, Reijo

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Article abstract of DOI:10.1107/S0108270199006307

In the title compound, CH₃(C₆H₅)₃P ⁺·C₃H₁₃B₁₀S^-, the negative charge of the sulfido group connected to the carborane cage is balanced by the phosphonium cation. In the cation, one of the three phenyl groups is disordered, exhibiting two orientations. In the anion, the C_cage-C_cage distance is 1.792 (5) A.

Full text of DOI:10.1107/S0108270199006307

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