Formal total synthesis of (-)-anisomycin based on the stereoselective nucleophilic substitution along with aryl migration

DOI: 10.1016/S0040-4039(99)01715-3

Source and publish data:

Tetrahedron Letters p. 8223 - 8226 (1999)

Update date:2022-08-04

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Authors:

Ono, Machiko

Suzuki, Keiko

Akita, Hiroyuki

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Article abstract of DOI:10.1016/S0040-4039(99)01715-3

The stereoselective conversion of (4R)-5-hydroxy-4-(4'-methoxyphenyl)-2(E)-pentenoate 5 into the (4S)-4-hydroxy-5-(4'-methoxyphenyl)-2(E)-pentenoate 6 using an AgNO₃/MS 4A/MeNO₂ system was accomplished along with complete inversion a

Full text of DOI:10.1016/S0040-4039(99)01715-3

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