Tetrahedron Letters p. 15 - 18 (1994)
Update date:2022-08-04
Topics:
Torret, J. A. De la
Fernandez, M.
Morgans, D.
Smith, David B.
Talamas, F. X.
Trejo, A.
N-allylhydroxamic acids 3 can be prepared by a novel thermal <3,3>-rearrangement of appropriate precursor O-tetrahydropyranylhydroximates 2.Such compounds are available from the protected hydroximoyl chlorides via alkoxide displacement.The rearrangement can proceed with modest chirality transfer.
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