LiAIH4 promoted reductive deoxygenation of hydroxybenzyl alcohols via benzoquinone methide intermediates

DOI: 10.1016/S0040-4039(98)01803-6

Source and publish data:

Tetrahedron Letters p. 8125 - 8128 (1998)

Update date:2022-08-03

Topics:

Authors:

Baik, Woonphil

Lee, Hyun Joo

Koo, Sangho

Kim, Byeong Hyo

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Article abstract of DOI:10.1016/S0040-4039(98)01803-6

Primary and secondary hydroxybenzyl alcohols react with LiAIH₄ in chlorobenzene to give the corresponding alkylphenols. The reaction proceeds through the formation of benzoquinone methide as an intermediate. An example of [4+2] cycloaddition of benzoquinone methide is also reported.

Full text of DOI:10.1016/S0040-4039(98)01803-6

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