A new path for the reductive cleavage of te-te bond by the system of Cp2TiCl2/i-BuMgBr and its utility in synthesis of unsymmetrical tellurides

Article abstract of DOI:10.1080/00397910008087163

The cleavage reduction of ditellurides by Cp₂TiCl₂/i- BuMgBr lead to nucleophilic tellurides [Cp₂TiTeAr]. This species reacts with aliphatic bromides to give unsymmetrical tellurides in good yield.

Full text of DOI:10.1080/00397910008087163

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Synthetic Communications: An
International Journal for Rapid
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Organic Chemistry
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A New Path for the Reductive
Cleavage of Te-Te Bond by the
System of Cp2TiCl2/i-BuMgBr
and ITS Utility in Synthesis of
Unsymmetrical Tellurides
Xian Huang a & Wei-Xin Zheng a
a Department of Chemistry , Xixi Campus, Zhejiang
University , Hangzhou, 310028, P. R. China
Published online: 04 Dec 2007.
To cite this article: Xian Huang & Wei-Xin Zheng (2000) A New Path for the Reductive
Cleavage of Te-Te Bond by the System of Cp2TiCl2/i-BuMgBr and ITS Utility in Synthesis
of Unsymmetrical Tellurides, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 30:8, 1365-1369, DOI:
10.1080/00397910008087163
To link to this article: http://dx.doi.org/10.1080/00397910008087163
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