
Journal of the American Chemical Society p. 7026 - 7033 (1999)
Update date:2022-07-31
Topics:
Hicks, Frederick A.
Buchwald, Stephen L.
The development of the first catalytic asymmetric Pauson - Khand type cyclization of enynes is described. The active catalyst, (S,S)-(EBTHI)Ti(CO)2 (1), is generated in situ from (S,S)-(EBTHI)TiMe2 (2). A variety of 1,6-enynes can be
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Doi:10.1021/ja01166a509
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