Carboxylation of styrenes with CBr4 and DMSO via cooperative photoredox and cobalt catalysis

DOI: 10.1039/c6ra28744a

Source and publish data:

RSC Advances p. 11233 - 11243 (2017)

Update date:2022-08-03

Topics:

Authors:

Song, Cai-Xia

Chen, Ping

Tang, Yu

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Article abstract of DOI:10.1039/c6ra28744a

Cooperative photoredox and cobalt catalyzed carboxylation of styrenes with CBr₄ to afford the corresponding α,β-unsaturated carboxylic acids has been realized through radical addition and Kornblum (DMSO) oxidation. DMSO serves as the oxidant, oxygen source and solvent under these photocatalytic conditions.

Full text of DOI:10.1039/c6ra28744a

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Product name:(E)-3-phenyl-2-(4-(trifluoromethyl)phenyl)acrylic acid

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