Co(II)PORPHYRIN CATALYZED ISOMERIZATION OF BICYCLOBUTANECARBONITRILE

DOI: 10.1016/S0040-4039(00)84877-7

Source and publish data:

Tetrahedron Letters p. 3669 - 3672 (1986)

Update date:2022-07-30

Topics:

Authors:

Miki, Sadao

Matsumura, Sei-ichiro

Ohno, Toshinobu

Yoshida, Zen-ichi

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Article abstract of DOI:10.1016/S0040-4039(00)84877-7

In the presence of catalytic amount of TPPCo(II), bicyclobutane-1-carbonitrile easily isomerized to cyclobutane-1-carbonitrile in 60-70 percent yield.Reaction behavior of other electronegative substituted bicyclobutanes in the presence of TPPCo(II) was also investigated.

Full text of DOI:10.1016/S0040-4039(00)84877-7

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