A New Indirect Application of Aggregative Activation: Synthesis of Esters by Cobalt-Catalyzed Carbonylation of Aryl, Heterocyclic, and Vinyl Halides under Atmospheric Pressure

DOI: 10.1021/jo00131a005

Source and publish data:

Journal of Organic Chemistry p. 8336 - 8340 (1995)

Update date:2022-08-04

Topics:

Authors:

Marchal, Joel

Bodiguel, Jacques

Fort, Yves

Caubere, Paul

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Article abstract of DOI:10.1021/jo00131a005

Sun lamp illuminated alkoxycarbonylation of aryl, heteroaryl, and vinyl halides was performed under atmospheric pressure of CO in the presence of a cobalt catalyst in situ generated from Co(OAc)2.Illunination through a Pyrex flask was sufficient to catalyze the reaction.This process avoids the use of Co2(CO)8 and excess CH3I, which were required in the earlier procedure.A S_RN1 mechanism is proposed.

Full text of DOI:10.1021/jo00131a005

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