Journal of Fluorine Chemistry p. 357 - 364 (1982)
Update date:2022-07-31
Topics:
Burdon, James
Parsons, Ian W.
Shommakhi, Ahmed
In 3H,4H-tetrafluoro-3-thiolen and 1H,2H-octafluorocyclohexene, the conversion of -CH=CH- into -CH=CF- by fluorination over KCoF4 takes place by saturation to -CHF-CHF- followed by dehydrofluorination, and not by direct replacement of a vinylic hydrogen.
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