Journal of the Chemical Society. Chemical communications p. 1251 - 1252 (1985)
Update date:2022-08-05
Topics:
Takeuchi, Hiroshi
Shiobara, Yukihiko
Mitani, Michiharu
Koyama, Kikuhiko
Reaction of phenyl azide with alkenes in the presence of ALCl3 gives an aziridinium-AlCl3 complex via an azide-AlCl3 complex; this reaction is followed by ring-opening reactions of the aziridinium-AlCl3 complex to give N-allylanilines and/or N-phenyl-β-chloroamines after work-up with aqueous Na2CO3, but the reaction with cis-cyclo-octene yields a novel aziridine, 9-phenyl-9-azabicyclo<6.1.0>nonane after the work-up.
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