Influence of an oxidising impurity on preparation of 2-lithio-1,3-dithiane: Isolation of bis[2-(1,3-dithianyl)]methanol

Article abstract of DOI:10.1080/00397919608005213

Bis-dithianylalkanols and dimers are formed in preparation of 2-lithio-1,3-dithianes due to the presence of oxidising impurity in n-BuLi (perhaps n-BuOOLi).

Full text of DOI:10.1080/00397919608005213

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Influence of an Oxidising
Impurity on Preparation of 2-
Lithio-1,3-dithiane: Isolation of
bis[2-d,3-Dithianyl)]methanol
Narshinha P. Argade a , Braja G. Hazra a & Padmakar
L. Joshi a
a Division of Organic Chemistry Synthesis , National
Chemical Laboratory , Pune, 411 008, India
Published online: 21 Aug 2006.
To cite this article: Narshinha P. Argade , Braja G. Hazra & Padmakar L. Joshi (1996)
Influence of an Oxidising Impurity on Preparation of 2-Lithio-1,3-dithiane: Isolation
of bis[2-d,3-Dithianyl)]methanol, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 26:15, 2797-2802, DOI:
10.1080/00397919608005213
To link to this article: http://dx.doi.org/10.1080/00397919608005213
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