Chemistry Letters p. 265 - 268 (1985)
Update date:2022-08-03
Topics: Rearrangement
Kudo, Kiyoshi
Mori, Sadayuki
Sugita, Nobuyuki
The direct hydrocarbonylation of methyl acetate to ethylidene diacetate by use of rhodium-palladium mixed catalysts with iodide and basic promoters in acetic acid solution was investigated at 160 deg under 200 kg/cm2 of synthesis gas(H2/CO=1/1).Conversion of methyl acetate up to 93percent and yield to ethylidene diacetate as high as 68percent were obtained.
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