Chemistry Letters p. 265 - 268 (1985)
Update date:2022-08-03
Topics: Rearrangement
Kudo, Kiyoshi
Mori, Sadayuki
Sugita, Nobuyuki
The direct hydrocarbonylation of methyl acetate to ethylidene diacetate by use of rhodium-palladium mixed catalysts with iodide and basic promoters in acetic acid solution was investigated at 160 deg under 200 kg/cm2 of synthesis gas(H2/CO=1/1).Conversion of methyl acetate up to 93percent and yield to ethylidene diacetate as high as 68percent were obtained.
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Doi:10.1021/jo00436a013
(1977)Doi:10.1021/jm00312a017
(1968)Doi:10.1039/c39940002511
(1994)Doi:10.1016/S0031-9422(00)89313-9
(1978)Doi:10.1016/j.tetlet.2003.12.034
(2004)Doi:10.1002/chem.201602197
(2016)
