Cyano and Thiocyanato-derivatives of the Hexachlorophosphate Ion (PCl6(1-))

DOI: 10.1039/DT9820001199

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1199 - 1204 (1982)

Update date:2022-07-30

Topics:

Authors:

Dillon, Keith B.

Platt, Andrew W. G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9820001199

The preparation and identification in solution of several new cyano- and thiocyanato-derivatives of the hexachlorophosphate (PCl6(1-)) ion are described.The cyano-complexes (1-) (n = 1-3) and the hexathiocyanatophosphate ion P(NCS)6(1-) have been isolated as tetra-n-alkylammonium salts and further characterised by elemental analysis, (31)P n.m.r., and (in some cases) vibrational spectroscopy.The mer isomer of the (1-) ion has been obtained pure and the fac isomer in a less pure state (ca. 3:1 fac:mer) by different preparative routes.Isomeric configurations in the chlorothiocyanatophosphate series (1-) have been assigned on the basis of the pairwise interaction method.

Full text of DOI:10.1039/DT9820001199

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Phosphorothioic triamide

Cas No:34217-67-9

R&D Labs maybe for 34217-67-9

xujianqiang

Contact:86-21-57725962

Address:shanghai
Hangzhou GreenCo Science & Technology Co., Ltd.

Contact:86-571-88257303

Address:1713 Room,Jingui Building,Gudun Road,Xihu District,Hangzhou,China
Weifang Dongxing Chitosan Factory

website:http://dxchitosan.lookchem.com/

Contact:13475651157

Address:Weifang city ,shandong province
Shanghai Standard Biotech Co., Ltd.

Contact:+86-18502101150

Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China
Hebei Tianxiang Biological & Pharmaceutical Co., Ltd

Contact:86-0312-6615158

Address:No 42 fazhan street qingyuan county

Relevant to this article

Diethylzinc-mediated allylation of carbonyl compounds catalyzed by [(NHC)(PR₃)PdX₂] and [(NHC)Pd(η³-allyl)Cl] complexes

Doi:10.1002/ejic.200900891
(2009)
Geminal Acylation-Alkylation at a Carbonyl Carbon via Regiospecifically Generated Metalloenamines

Doi:10.1021/ja00538a027
(1980)
Doi:10.1016/S0040-4039(01)97291-0
(1971)
Ring-deactivated hydroxymethylpyrroles as inhibitors of α-chymotrypsin

Doi:10.1016/S0968-0896(00)00274-1
(2001)
Tautomerism in the solid state and in solution of a series of 6-aminofulvene-1-aldimines

Doi:10.1021/jo010625v
(2002)
Doi:10.1002/hlca.19710540620
(1971)

Article Doi