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Cyano and Thiocyanato-derivatives of the Hexachlorophosphate Ion (PCl6(1-))

DOI: 10.1039/DT9820001199

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1199 - 1204 (1982)

Update date:2022-07-30

Topics:

Authors:

Dillon, Keith B.Dillon, Keith B.

Platt, Andrew W. G.Platt, Andrew W. G.

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Article abstract of DOI:10.1039/DT9820001199

The preparation and identification in solution of several new cyano- and thiocyanato-derivatives of the hexachlorophosphate (PCl6(1-)) ion are described.The cyano-complexes (1-) (n = 1-3) and the hexathiocyanatophosphate ion P(NCS)6(1-) have been isolated as tetra-n-alkylammonium salts and further characterised by elemental analysis, (31)P n.m.r., and (in some cases) vibrational spectroscopy.The mer isomer of the (1-) ion has been obtained pure and the fac isomer in a less pure state (ca. 3:1 fac:mer) by different preparative routes.Isomeric configurations in the chlorothiocyanatophosphate series (1-) have been assigned on the basis of the pairwise interaction method.

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