Helvetica Chimica Acta p. 1083 - 1091 (1981)
Update date:2022-09-26
Topics:
Fischer, Matthias
Veith, Hans Juergen
The collision-induced fragmentations of 2- and 3-phenyl substituted alkylalkylidene iminium ions are reported.Besides the homolytic cleavage of the aza-allyl bond a nucleophilic attack of the unsubstituted phenyl group at the iminium function is observed in the gas phase, yielding carbonium ions such as cyclopropan-spirobenzenium (3), indanylium (10) and indenylium ions (11).
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