Tetrahedron Letters p. 1975 - 1978 (1983)
Update date:2022-08-05
Topics: Radical reactions Isomerization Cycloaddition Reactions Insertion reactions
Meriem, Abdelkader
Majoral, Jean-Pierre
Revel, Monique
Navech, Jacques
Photolysis of phosphaalkenes leads to an inversion of polarity of the phosphorus carbon double bond and to a cleavage into transient phosphinidene and carbene; unexpected alcoholysis of a PIII-C bond and the <4+2> cycloaddition of a linear phosphaalkene on a diene are also reported.
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