Regioselective Rh2(OAc)4-Promoted Reactions of Methyl Diazoacetate with Terminal Triple Bond Enynes

DOI: 10.1039/P29940000709

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 709 - 714 (1994)

Update date:2022-08-05

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Authors:

Shapiro, Evgeny A.

Kalinin, Alexey V.

Ugrak, Bogdan I.

Nefedov, Oleg M.

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Article abstract of DOI:10.1039/P29940000709

The selective Rh2(OAc)4-promoted methoxycarbonylmethylenation of a triple bond in enynes, with a terminal triple bond, by methyl diazoacetate is established, and the main factors, affecting the regioselectivity of the process, are elucidated.The easy in s

Full text of DOI:10.1039/P29940000709

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