Aspects of the Inorganic Chemistry of Rubber Vulcanisation. Part 2. Anionic Mixed-ligand Zinc Complexes derived from Dialkyldithiocarbamates, 2-Mercapto-benzothiazole, -benzoxazole, and -benzimidazole, and the Crystal and Molecular Structures of , <Zn(C7H...

DOI: 10.1039/DT9800001945

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1945 - 1957 (1980)

Update date:2022-08-05

Topics:

Authors:

McCleverty, Jon A.

Morrison, Norman J.

Spencer, Neil

Ashworth, Christopher C.

Bailey, Neil A.

et al. et al.

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Article abstract of DOI:10.1039/DT9800001945

The complexes ^- (R=Me or Et), ^- , ^- (C7H4NS2=benzothiazole-2-thiolate), ^- , ^- , ^- , ^- , and (C7H5N2S)2>^- (C7H5N2S=benzimidazole-2-thiolate) have been isolated as their ⁺ and ⁺ salts.The compounds , , (R''=Me or n-Bu), , and (C3H4NS2=thiazoline-2-thiolate) have also been prepared.The structures of the four title complexes have been determined crystallographically.The nature of the distortions from regular co-ordination geometries in some of these species are discussed and related to the molecular structures of <2> (R=Me or Et).

Full text of DOI:10.1039/DT9800001945

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