Chemistry Letters p. 280 - 281 (2010)
Update date:2022-09-26
Topics:
Yadav
Reddy, B. V. Subba
Mishra, Anand Kumar
1,3-Dicarbonyl compounds undergo smooth allylation, benzylation, propargylation, and acylation with halides using metallic zinc in DMF at 60 °C to afford the corresponding allyl, benzyl, 2-propynyl, and acylated 1,3-diesters in good yields. In the case of cyclic 1,3-diketones, the corresponding enol ethers are obtained as sole products instead of C-alkylation.
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