Journal of the Chemical Society. Chemical communications p. 1754 - 1756 (1986)
Update date:2022-08-04
Topics:
Laurent, Pascale
Tanguy, Guy
Abbayes, Herve des
Acyltetracarbonyliron anions RCOFe(CO)4(1-) (3) are readily synthesised under mild phase transfer (PT) conditions from pentacarbonyliron and reactive organic halides; the in situ generated anions (3) (R = ArCH2) are the true catalysts in the PT carbonylation of benzyl halides to give ketones or carboxylic acids.
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