Tetrahedron p. 5147 - 5152 (1993)
Update date:2022-09-26
Topics:
Casuscelli, Francesco
Chiacchio, Ugo
Liguori, Angelo
Romeo, Giovanni
Sindona, Giovanni
Uccela, Nicola
High yield conversion of 3,5,5-triarylisoxazolidines into indene derivatives has been achieved by 4 h refluxing in aq.H2SO4.The rearrangement pathway is interpretable on the basis of a ring-opening process where the crucial step is the protonation of the oxygen atom of the isoxazolidine nucleus.MNDO calculations performed on N,N,O-trimethylhydroxylamine chosen as a model system support the proposed mechanism.
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Doi:10.1002/jlcr.2590080209
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(2018)Doi:10.1039/c39740000647
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(1972)