Ruthenium amidinato-carbene complexes containing a Ru-Si bond: Formation and reversible α-silyl group migration from the metal to the carbene ligand

DOI: 10.1021/om010775w

Source and publish data:

Organometallics p. 4996 - 4998 (2001)

Update date:2022-07-30

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Authors:

Hayashida, Taizo

Nagashima, Hideo

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Article abstract of DOI:10.1021/om010775w

Reactions of the coordinatively unsaturated complexes [(η⁶-C₆Me₆)Ru{η-ⁱPrNC(Me) = NⁱPr}]⁺X^- with Me₃SiCHN₂ resulted in the formation of the amidinato-carbene complexes [(η⁶-C₆Me₆)Ru{=CHNⁱPrC(Me) = NⁱPr}(SiMe₃)]⁺ X^-, in which a trimethylsilyl group is bonded to the ruthenium atom. Migration of the silyl group to the carbene ligand occurred on reaction with CO, whereas the reverse reaction was promoted by photochemical dissociation of CO.

Full text of DOI:10.1021/om010775w

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Product name:C₆(CH₃)6Ru(CNC₄H₉)Si(CH₃)3CHNC₃H₇CCH₃NC₃H₇⁽¹⁺⁾*B((CF₃)2C₆H₃)4^(1-)=C₆(CH₃)6Ru(CNC₄H₉)SiC₁₂H₂₇N₂B((CF₃)2C₆H₃)4

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