Tetrahedron p. 14327 - 14338 (1997)
Update date:2022-09-26
Topics:
Jiang, Yaozhong
Gong, Liuzhu
Feng, Xiaoming
Hu, Wenhao
Pan, Weidong
Li, Zhi
Mi, Aiqiao
Chiral selen-titanium complexes were found to be efficient catalysts for the enantioselective trimethylsilylcyanation of aldehydes. An enantioselectivity up to 87.1% e.e, was obtained by using 10mol% Ti(IV)-salen 2d as catalyst. The reaction mechanism was
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