APPROCHE CINETIQUE DU MECHANISME D'ISOMERISATION DE SPIROPHOSPHORANES OPTIQUEMENT ACTIFS

DOI: 10.1016/0040-4020(82)85158-2

Source and publish data:

Tetrahedron p. 2111 - 2122 (1982)

Update date:2022-08-03

Topics:

Authors:

Klaebe, A.

Brazier, J. F.

Cachapuz Carrelhas, A.

Garrigues, B.

Marre, M. R.

Contreas, R.

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Article abstract of DOI:10.1016/0040-4020(82)85158-2

The polarimetric kinetic study, of the epimerisation of optically pure spirophosphoranes derived from α-aminoalcohols or α-aminoacids, leads to mechanistic conclusions.Evidence from isotopic, solvent and concentration effects and values of the activation

Full text of DOI:10.1016/0040-4020(82)85158-2

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