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Synthetic Studies of Withanolides. Part 2. Synthesis of 4aβ,5β-Epoxy-4a,5,6,7,8,8a-hexahydro-4β-hydroxy-8aβ-methylnaphthalen-1(4H)-one and Related Compounds

DOI: 10.1039/P19810000088

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 88 - 93 (1981)

Update date:2022-07-29

Topics:

Authors:

Hirayama, MasaoHirayama, Masao

Fukatsu, ShunzoFukatsu, Shunzo

Ikekawa, NobuoIkekawa, Nobuo

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Article abstract of DOI:10.1039/P19810000088

The title compounds, a simple AB ring moiety of withaferin A, and its seven isomers, were synthesized via octahydro-4a-hydroxy-5-(phenylthio)-8a-methylnaphthalen-1(2H)-ones <(5a) and (5b)>.The key steps in the synthesis involve either 1,2-phenylthio-migra

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