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for further studies).
In conclusion, we described the first example of substrate
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indicate controlled polymerization processes. In addition, the
one-pot copolymerization of the two monomers to give a block
copolymer was also achieved by using the titanium analogue.
Further copolymerization studies and mechanistic investiga-
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ASSOCIATED CONTENT
* Supporting Information
Synthetic details, NMR spectra, and data from kinetics,
electrochemistry, and crystallographic studies. This material is
■
S
AUTHOR INFORMATION
Corresponding Author
■
Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENTS
■
This work was supported by the NSF (Grants 0847735 and
1362999) and the donors of the American Chemical Society
Petroleum Research Fund. The NMR spectroscopic work was
supported by the National Science Foundation under equip-
ment grant no. CHE-1048804.
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