Bioscience, Biotechnology and Biochemistry p. 887 - 891 (2002)
Update date:2022-08-04
Topics:
Ohira, Susumu
Akiyama, Megumi
Kamihara, Kumiko
Isoda, Yuichi
Kuboki, Atsuhito
(1S,3R)-1-Aminocyclopentane-1,3-dicarboxylic acid (ACPD), a potent agonist of metabotropic glutamate receptors, was synthesized from L-serine. The chiral quaternary center was constructed by C-H insertion of the alkylidenecarbene, this being generated by the reaction between lithiotrimethylsilyldiazomethane and the corresponding ketone.
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Doi:10.1002/1099-0690(200207)2002:14<2298::AID-EJOC2298>3.0.CO;2-E
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