Tetrahedron Letters p. 2743 - 2746 (1985)
Update date:2022-08-05
Topics:
Walborsky,H.M.
Duraisamy,M.
Treatment of (S)-(+)-1-chloro-2,2-diphenylcyclopropane with n-butyllithium at -25 deg C yield, inter alia, (R)-(-)-1-n-butyl-2,2diphenylcyclopropane with overall inverted configuration.A metal assisted ionization mechanism is proposed.
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