
Journal of the Chemical Society. Chemical communications p. 457 - 458 (1986)
Update date:2022-09-26
Topics:
Krief, Alain
Clarembeau, M.
Barbeaux, Ph.
Benzyl-lithiums, readily available from benzyl methyl selenides and alkyl-lithiums, are efficiently alkylated; this reaction allows the geminal dialkylation of the carbonyl groups of aromatic aldehydes and ketones and the geminal aryl-alkylation of aliphatic analogues.
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